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两种悬钩子属植物化学成分研究
Studies on the Chemical Constituents of Two Species of Raspberry (Rubus L.)
【摘要】 首次对紫色悬钩子 Rubus irritans Focke和菰帽悬钩子R. pileatus Focke的化学成分进行了研究。从其地上部分的乙醇提取物经各种柱层析方法分离纯化分别得到6个和5个化合物,运用光谱方法和与标准品对照分别鉴定为:2α,3β,19α-三羟基乌索-12-烯-28-酸(Ⅰ),2α,3β,19α,23-四羟基乌索-12-烯-28-酸(Ⅱ),2α,3β,19α,23-四羟基齐墩果-12-烯-28-酸(Ⅲ),2α,3β,19α,24-四羟基乌索-12-烯-28-酸(Ⅳ),3β,19α-二羟基乌索-12-烯-24,28-二酸(Ⅴ),乌索酸(Ⅵ),齐墩果酸(Ⅶ),卜胡萝卜苷(Ⅷ)和β-D-(-)-吡喃果糖(Ⅸ)。这些化合物均为首次从该两种植物中分得。
【Abstract】 Six and five compounds have been isolated respectively from Purple Raspberry (Rubus irritans Focke) and Cap form Raspberry (Rubus pileatus Focke). Based on chemical and spectral evidences, or by comparison with authentic samples, the structures of these compounds were elucidated as 2α, 3β, 19α- trihydroxyurs-12-en-28-cio acid (Ⅰ), 2α, 3β, 19α, 23-tetrahydroxyurs-12-en-28-oic acid (Ⅱ),2α, 3β, 19α, 23tetrahydroxyolean-12-en-28-cio acid(Ⅲ), 2α, 3β, 19α, 24-tetrahydroxyurs-12-en-28-acid (Ⅳ),3β 19α dihydroxyurs-12-en-24, 28-dioic acid(Ⅴ), uroslic acid (Ⅵ) , oleanolic acid (Ⅶ), daucosterol(Ⅷ), and β- Dpyranofructose (Ⅸ). All these cmpounds were isolated for the first time from these two species of Rubus L.
- 【文献出处】 中草药 ,CHINESE TRADITIONAL AND HERBAL DRUGS , 编辑部邮箱 ,1999年02期
- 【分类号】R284
- 【被引频次】19
- 【下载频次】383