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苯乙烯和甲基丙烯酸环氧丙酯共聚物单分散粒子的合成

Preparation of Monodisperse Particles of Styrene/Glycidyl Methacrylate Copolymer

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【作者】 唐康泰杨治中付英毅刘雪宁区晖

【Author】 Tang Kangtai; Yang Zhizhong;Fu Yingyi;Liu Xuening; Ou Hui(Guangzhou Institute of Chemistry, Chminese Academy of Sciences,Guangzhou 510650)

【机构】 中国科学院广州化学研究所!广州510650

【Abstract】 The dispersion copolmerization fo styrene and glycidyl methacrylate(GMA) in methanol-ethanol mixutre has been studied. The monodisperse particles prepared have sizes ranged in 1. 4 to 6. 5 μm.The effects of solubility parameter of solvents,reaction temperature and monomer ratio on the copolymer particle formation have been examined .It is found that the greater the solubility parameter difference of the solvent and polymer and the greater the content of GMA,the smaller the size of copolymer particle .When polymerization was carried out at low temperature, small particles were obtained.

  • 【文献出处】 应用化学 ,CHINESE JOURNAL OF APPLIED CHEMISTRY , 编辑部邮箱 ,1999年06期
  • 【分类号】TQ24
  • 【被引频次】3
  • 【下载频次】115
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