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堆制处理过程中的多环芳烃降解

DEGRADATION OF POLYCYCLIC AROMATIC HYDROCARBONS IN COMPOSTING OF SOIL

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【作者】 张文娟沈德中张从孟明宝韩清鹏

【Author】 ZHANG Wenjuan , SHEN Dezhong , ZHANG Cong , MENG Mingbao 1 & HAN Qingpeng ( China Agricultural University , Beijing 100094) ( 1 Beijing Environmental Monitoring Center , Beijing 100044)

【机构】 中国农业大学资源与环境学院!北京100094北京市环境保护监测中心!北京100044

【摘要】 用实验室模拟方法,研究了堆制处理过程对污染土壤中4 ~6 环的多环芳烃(PAHs) 的降解. 结果表明,堆制对6 种难降解的PAHs 都有不同程度的降解作用,PAHs 的降解随着苯环数的增加而降低,其去除率的大小顺序为荧蒽> 苯并[a] 蒽、苯并[a] 芘> 苯并[b] 荧蒽、苯并[k] 荧蒽> 苯并[ghi] 北. 其中,荧蒽的去除率为46.0 % ~92.9% ;苯并[a] 蒽的去除率为7.7% ~37 .2 % . 当PAHs 的初始浓度提高约50 倍时,除荧蒽外其它PAHs 的降解随着污染浓度的提高而降低. 不同C/N均有类似的规律,但C/N25:1 比C/N40:1 为好. 堆中各种PAHs 浓度在高温期以前都有所提高,但在降温期以后又有不同程度的降低. 细菌总数测定表明,数量变化呈双峰型.

【Abstract】 Laboratory scale test was conducted to evaluate the degradation of polycyclic aromatic hydrocarbons(PAHs) in composting of soil. Six PAHs were involved, including fluoranthene (FA), benzo[a]anthracene (B[a]A), benzo[b]fluoranthene (B[b]F), benzo[k]fluoranthene (B[k]F), benzo[a]pyrene (B[a]P) and benzo[g,h,i]perylene(B[ghi]Pe). The results indicated that all PAHs were degraded to some extent in the composting. The order of the percentage of PAHs loss was FA, B[a]A, B[a]P, B[b]F, B[k]F and B[ghi]Pe. Among those, FA removal rate was 46.0%~92.9% and B[a]A 7.7%~37.2%. The removal rates of the most PAHs decreased with rise of initial PAHs concentration, except FA. Similar rule was found in different C/N ratios (25:1~40:1), but 25:1 was better. The concentrations of PAHs increased during the temperature increasing stage and thermophic stage of the composting, but decreased during the temperature decreasing stage and curing stage. Total count of bacteria in the composting had two peak values.

【基金】 国家自然科学基金!(No:29577269)
  • 【文献出处】 应用与环境生物学报 ,CHINESE JOURNAL OF APPLIED AND ENVIRONMENTAL BIOLOGY , 编辑部邮箱 ,1999年06期
  • 【分类号】O625.15;X705;S141.
  • 【被引频次】40
  • 【下载频次】184
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