节点文献
合欢皂苷J20的结构鉴定
STRUCTURAL ELUCIDATION OF JULIBROSIDE J 20
【摘要】 目的:研究合欢皮的化学成分及活性。方法:用现代色谱法分离合欢皮皂苷,用化学和现代波谱法,主要是二维核磁共振技术鉴定结构。结果及结论:分离并鉴定了一个新三萜皂苷,结构为3O[βD吡喃木糖基(1→2)αL吡喃阿拉伯糖基(1→6)βD吡喃葡糖基]21O{(6S)2反式2羟甲基6甲基6OβD吡喃木糖基2,7辛二烯酰基}金合欢酸28OβD吡喃葡糖基(1→3)[αL呋喃阿拉伯糖基(1→4)]αL吡喃鼠李糖基(1→2)βD吡喃葡糖基酯,命名为合欢皂苷J20(JulibrosideJ20)。
【Abstract】 AIM: To research the constituents and activities of Albizzia julibrissin . METHODS: The saponins were separated by using HPLC and the structures were identified on the basis of chemical and spectral analysis. RESULTS AND CONCLUSION: A new saponin was isolated and its structure was elucidated as 3 O [β D xylopyranosyl (1→2) α L arabinopyranosyl (1→6) β D glucopyranosyl] 21 O [(6S) 2 trans 2 hydroxymethyl 6 methyl 6 O β D xylopyranosyl 2,7 octadienoyl] acacic acid 28 O β D glucopyranosyl (1→3) [α L arabinofuranosyl (1→4)] α L rhamnopyranosyl (1→2) β D glucopyranosyl ester.
【Key words】 Albzzia julibrissin Durazz.; triterpenoid saponin; julibrosid J 20;
- 【文献出处】 药学学报 ,ACTA PHARMACEUTICA SINICA , 编辑部邮箱 ,1999年07期
- 【分类号】R284.1
- 【被引频次】13
- 【下载频次】169