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低分子量EVA的合成及对柴油的降凝作用
SYNTHESIS OF ETHYLENE VINYL ACETATE COPOLYMER(EVA) WITH LOW MOLECULAR WEIGHT AND ITS PERORMANCE PROPERTIES AS POUR POINT DEPRESSANT FOR DIESEL OIL
【摘要】 采用低压溶液自由基聚合方法得到了数均分子量在1000—4000 之间的低分子量乙烯醋酸乙烯酯共聚物( EVA),用红外、核磁、凝胶渗透色谱对共聚物结构进行了表征,探讨了引发剂浓度、反应温度、反应压力、聚合溶剂等对共聚物分子量、分子量分布以及共聚物组成的影响,研究了低分子量EVA对柴油的降凝作用。
【Abstract】 Ethylene vinyl acetate copolymer(EVA) with molecular weight M n=1000-4000 was synthesized by free radical polymerization in organic solution under low pressure. The structure of the copolymer obtained was confirmed by FTIR, 1H NMR, and GPC data. The influences of initiator concentration, temperature, pressure, and polymerization solvent on polymer structure were investigated. it was also showed that EVA with low molecular weight was a good pour point depressant for diesel oil.
【关键词】 乙烯-醋酸乙烯酯共聚物(EVA);
低分子量;
合成;
降凝剂;
柴油;
【Key words】 Ethylene Vinyl Acetate Copolymer(EVA); Low Molecular Weight; Synthesis; Pour Point Depressant; Diesel Oil;
【Key words】 Ethylene Vinyl Acetate Copolymer(EVA); Low Molecular Weight; Synthesis; Pour Point Depressant; Diesel Oil;
- 【文献出处】 油田化学 ,OILFIELD CHEMISTRY , 编辑部邮箱 ,1999年04期
- 【分类号】TE869
- 【被引频次】23
- 【下载频次】426