【摘要】 采用Diels-Alder方法合成了2,3-萘二腈和6,7-二溴-2,3-萘二腈化合物,并以此为前体成功地合成了相应的钴萘酞菁系列化合物——一种新型的功能有机材料。另外还探讨了酞菁形成的机理,并讨论了若干影响因素。这些化合物具有较好的稳定性,在胺类或其它含氮的有机溶剂中有较好的溶解度,如苯胺、二甲基甲酰胺(DMF)或吡啶等。更多还原

【Abstract】 2,3- Naphthalocyaninatocobalt compounds, a new type of functional materials, have been successfully prepared by using of Diels - Alder reaction. The mechanism of the synthetic reactions and the factors which have influence on reactions are discussed. Despite their insolubility in many organic solvents, they are found to be soluble in nitrogen - containing solvents, such as DMF and pyridine.更多还原