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低压离子色谱法测定水样和地质样品中的Li~+、Na~+、K~+离子

Determination of Cations(Li~+,Na~+,K~+) in Water and Geological Samples by Low Pressure Ion Chromatography

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【作者】 吴永康朱刚敖艳

【Author】 WU Yong-kang, ZHU Gang,AO Yan (Chemistry Dept. Southwest Institute for Nationalities Chengdu 610041)

【机构】 西南民族学院化学系!成都610041

【摘要】 介绍了低压离子色谱仪测定水样(地下水和自来水)和地质样品中Li~+、Na~+、K~+离子的方法.待测阳离子在色谱柱上被分离,以 8.64×10-4mol·L-1HNO3溶液作流动相,流速为1.2ml·min-1经电导检测器(进样量为1.2ml·min-1经电导检测器),进样量为40μl时,Li~+、Na~+、K~+的检出限分别为0.030,0.410,0.460μg·ml-1.

【Abstract】 A method for determining cations in water samples(well-, tap-water) and geological samples by low pressure ion chromatography is reported. Li~+, Na~+, K~+ have been saparated on a seperation column. The mobile phase used was 8.64 × 10-4mol.I-1 IHNO3 at the flow rate of 1.15ml ·min-1. Cations in fractions that eluted from the column were daterminated by conductor. Detection limits were 30ng. ml-1 for Li~+, 410ng·ml-1 for Na~+, 460ng·ml-1 for K+, for a 40ul injection.

【关键词】 低压离子色谱水样地质样Li~+Na~+K~+
【Key words】 low pressure chromatographywater samplesgeological samplesLi~+Na~+K~+
  • 【文献出处】 西南民族学院学报(自然科学版) ,JOURNAL OF SOUTHWEST NATIONALITIES COLLEGE(NATURAL SCIENCE EDITION) , 编辑部邮箱 ,1999年04期
  • 【分类号】O657.7
  • 【被引频次】3
  • 【下载频次】78
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