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低压离子色谱法测定水样和地质样品中的Li~+、Na~+、K~+离子
Determination of Cations(Li~+,Na~+,K~+) in Water and Geological Samples by Low Pressure Ion Chromatography
【摘要】 介绍了低压离子色谱仪测定水样(地下水和自来水)和地质样品中Li~+、Na~+、K~+离子的方法.待测阳离子在色谱柱上被分离,以 8.64×10-4mol·L-1HNO3溶液作流动相,流速为1.2ml·min-1经电导检测器(进样量为1.2ml·min-1经电导检测器),进样量为40μl时,Li~+、Na~+、K~+的检出限分别为0.030,0.410,0.460μg·ml-1.
【Abstract】 A method for determining cations in water samples(well-, tap-water) and geological samples by low pressure ion chromatography is reported. Li~+, Na~+, K~+ have been saparated on a seperation column. The mobile phase used was 8.64 × 10-4mol.I-1 IHNO3 at the flow rate of 1.15ml ·min-1. Cations in fractions that eluted from the column were daterminated by conductor. Detection limits were 30ng. ml-1 for Li~+, 410ng·ml-1 for Na~+, 460ng·ml-1 for K+, for a 40ul injection.
【关键词】 低压离子色谱;
水样;
地质样;
Li~+;
Na~+;
K~+;
【Key words】 low pressure chromatography; water samples; geological samples; Li~+; Na~+; K~+;
【Key words】 low pressure chromatography; water samples; geological samples; Li~+; Na~+; K~+;
- 【文献出处】 西南民族学院学报(自然科学版) ,JOURNAL OF SOUTHWEST NATIONALITIES COLLEGE(NATURAL SCIENCE EDITION) , 编辑部邮箱 ,1999年04期
- 【分类号】O657.7
- 【被引频次】3
- 【下载频次】78