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电沉积Ni La P合金上析氢的研究

Study of electrochemical behavior of hydrogen evolution on electrodeposited nickel lanthanum phosphorus alloy in aqueous solution

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【作者】 吴俊黄清安喻敬贤

【Author】 WU Jun, HUANG Qing an, YU Jing Xian (College of Chem and Environmental Science, WUHAN Univ, Wuhan 430072 China)

【机构】 武汉大学化学与环境科学院!湖北武汉430072

【摘要】 在1 mol·L- 1  KOH 水溶液中测量了Ni 电极和NiLaP合金电极上析氢反应的极化曲线.实验结果表明,与镍电极相比,NiLaP合金电极上析氢的速度比Ni 电极约大10 倍,析氢电势正移200 ~300 mV( 在ic = 100~150mA·cm - 2) .显示出NiLaP合金具有较高的析氢催化活性,有利于降低槽电压,减少能耗.

【Abstract】 The cathodic polarization curves on electrodeposited nickel lanthanum phosphorus alloy and nickel electrode in 1 mol.L\+\{-1\} potassium hydroxide solution were measured. It is showed that the rate of hydrogen evolution on the Ni La P alloy was ten times more than that of nickel electrode and that the hydrogen evolution potential on the cathode of Ni La P alloy moved positively compared with nickel cathode, which is about 200~300 mV for the Ni La P alloy at i\-c=100 150A·cm\+\{-2\}. The Ni La P alloy was provided with high catalytic activity of hydrogen evolution that can reduce the both voltage and energy loss during electrolysis of sodium chloride.

【基金】 国家自然科学基金资助
  • 【文献出处】 武汉水利电力大学学报 ,JOURNAL OF WUHAN UNIVERSITY OF HYDRAULIC AND ELECTRIC ENGINEERING , 编辑部邮箱 ,1999年05期
  • 【分类号】O646.54
  • 【被引频次】13
  • 【下载频次】83
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