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CH₂（³B₁）与NO的基元化学反应研究

TR-FTIR Study of the Reaction CH₂（■³B₁） + NO

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【Author】 Yang Jixin;Su Hongmei;Mao Wentao;Zhong Jinxian;Kong Fan’ao(The State Key Laboratory of Molecular Reaction Dynamics,Institute of Chemistry Chinese Academy of Science,Beijing 100080; Research Center for Eco-Environmetal Sciences, Chinese Academy of Science

【机构】中国科学院生态环境研究中心!北京； 100085；中国科学院化学研究所分子反应动力学国家重点实验室!北京； 100080； 1；

【Abstract】 The reaction of methylene radicals in their 3 B1 electronic ground state with molecular NO was studied. Pure CH2(X 3 B1 ) radicals were prodced by UV photolysis of ketene at 351 nm.The products were measured by Time-Resolved Fourier Transform Infrard (TR-FTIR) spectrometer. CO.OH .NH2 and HOCN or its isomer HNCO were found as primary prodcts and several possible channels of this reaction were suggested.更多还原