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含镓、锡的铝合金在碱性溶液中的阳极行为

The Electrochemical Behavior of Al Alloys Containing Tin and Gallium in Alkaline Electrolytes

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【作者】 李振亚秦学余远彬陈艳英易玲杨林

【Author】 li Zhenya; Qin Xue; Yu Yuanbin; Chen Yanying; Yi ling; Yang lin (Tisnjin University Tianjin 300072)

【机构】 天津大学化工学院!天津300072

【Abstract】 The major reason of Al anode activation is that Ga can plate out on the aluminum surface and form activated points. The Al-Sn, Al - Ga binary alloys can’t be activat6d in alkaline medium. During the dissolution of the Al - Sn - Ga ternary anode, Sn and Ga dissolove solution aions as ions. After Sn ions deposit on the surface of Al anode, Ga ions will underpotentially deposit on Sn. The higher activation of the polycomponent alloy anode is caused by much more new activated points being continually formed. The activation mechanism for the polycomponent Al-alloy anode in alkaline medium is abided by the" di ssolution-deposition".

【关键词】 铝阳极活化欠电位沉积
【Key words】 Al anodeActivationUnderpotential deposition
  • 【文献出处】 物理化学学报 ,ACTA PHYSICO-CHIMICA SINICA , 编辑部邮箱 ,1999年04期
  • 【分类号】O646
  • 【被引频次】51
  • 【下载频次】186
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