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简单级数反应的特征时间法
Characteristic time Mathod for Simple Order Reactions
【Abstract】 On the theoretical basis of thermokinetics, a thermdeinetic research methed for simple order reactions - Characteristic time methed has been proposed in this pape.The method only ed characteristic data of thermoanalytic curve tm, m. and A, and uses data processing on compuer to give rate constant. In order to test the validity of thes methed,the saponificaion of ethyt butyrate and ethyt benzoate in aqueous ethanol solven and the fonnation of hexamethylene tetramine in aqueous solution have been studied.The rate constants calculated with this method are in agreement with those in the literatures , and therefore, the characteristic time method for simple crder reactions is beieved to be correct.
【关键词】 热动力学;
热动力学研究方法;
特征时间法;
简单级数反应;
【Key words】 Thennokinetics; Thermokinetic research method; Chateristic time methed; Simple order reaction;
【Key words】 Thennokinetics; Thermokinetic research method; Chateristic time methed; Simple order reaction;
- 【文献出处】 物理化学学报 ,ACTA PHYSICO-CHIMICA SINICA , 编辑部邮箱 ,1999年04期
- 【分类号】O643
- 【下载频次】97