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简单级数反应的特征时间法

Characteristic time Mathod for Simple Order Reactions

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【作者】 陈勇谢家庆张元勤曾宪诚

【Author】 Chen Yong; Xie Jiaqing; Zhang Yuanqing; Zeng Xiancheng (Department of Chemistry Sichuan University, Chengdu 610064)

【机构】 四川大学化学系!成都610064自贡师专化学系

【Abstract】 On the theoretical basis of thermokinetics, a thermdeinetic research methed for simple order reactions - Characteristic time methed has been proposed in this pape.The method only ed characteristic data of thermoanalytic curve tm, m. and A, and uses data processing on compuer to give rate constant. In order to test the validity of thes methed,the saponificaion of ethyt butyrate and ethyt benzoate in aqueous ethanol solven and the fonnation of hexamethylene tetramine in aqueous solution have been studied.The rate constants calculated with this method are in agreement with those in the literatures , and therefore, the characteristic time method for simple crder reactions is beieved to be correct.

  • 【文献出处】 物理化学学报 ,ACTA PHYSICO-CHIMICA SINICA , 编辑部邮箱 ,1999年04期
  • 【分类号】O643
  • 【下载频次】97
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