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CO2对Cu-Ce-O催化剂催化氧化CO活性的影响

The Effect of CO2 on Catalytic Activity of Cu-Ce-O Complex Oxides for CO Oxidation

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【作者】 刘英骏; 张继军; 李能; 林炳雄;

【Author】 Liu Yingjun; Zhang Jijun; Li Neng; Lin Bingxiong(Institute of Physical Chemistry, Peking University,Beijing 100871)

【机构】 北京大学物理化学研究所!北京; 100871;

【Abstract】 The efect of CO2 on catalytic activity for CO oxidation on Cu-Ce-O fluorite-type complex oxides has been investigated. CO2 played an inhibiting role in CO oxidation on the cat-alyst simlar to what happened on CeO2. As CO2 was introduced into the feed, the coliversion of CO to CO2 on the catalyst was reduced a little. At room temperature,the catalyst could easily adsorb CO2 in large amounts from the air to fbrm carbonate on its surtace.as well as from the yields at low reaction temperature As a restit,the catalyst could be poisoned by CO2 tentatively.The catalytic activity could be recovered to its imitial value on being heated at 300 ℃ or highertemperature.Cu-Ce-O catalyst showed high activity with CO conversion over 98% after being pretreated to desorb CO2 previously.

  • 【文献出处】 物理化学学报 ,ACTA PHYSICO-CHIMICA SINICA , 编辑部邮箱 ,1999年02期
  • 【分类号】O643
  • 【被引频次】16
  • 【下载频次】92
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