【摘要】 在甲醇乙腈水介质中将邻菲咯啉（ Ｐｈｅｎ）的 Ｃｕ（Ⅱ）、 Ｚｎ（Ⅱ）、 Ｐｂ（Ⅱ）配合物，２，２联吡啶（ Ｂｉｐｙ）的 Ｚｎ（Ⅱ）、 Ｐｂ（Ⅱ）配合物及乙二胺（ Ｅｎ）的 Ｃｕ（Ⅱ）、 Ｚｎ（Ⅱ）配合物分别与 ２，３二氯５，６二氰基对苯醌阴离子的季铵盐（ Ｅｔ４ Ｎ Ｄ Ｄ Ｑ）反应，合成了未见报道的７ 个含 Ｄ Ｄ Ｑ 的金属配合物经元素分析确定了配合物的组成通过 Ｉ Ｒ、 Ｕ Ｖ Ｖｉｓ、 Ｅ Ｓ Ｒ、摩尔电导及固体电导的测定对其结构及性质进行了研究更多还原

【Abstract】 Seven new complexes containning 2,3 dichloro 5,6 dicyano benzoquinone radical anion(DDQ  ) were prepared by the reaction of Et 4NDDQ with M(Phen) 2X 2(Phen=o phenanthroline; M=Cu、Zn, X=Cl; M=Pb, X=NO 3), M(Bipy) 2X 2(Bipy=2,2 bipyridine; M=Zn, X=Cl; M=Pb, X=NO 3), or M(En) 2Cl 2(En=ethylenediamine, M=Cu, Zn) respectively in methanol acetonitrile water media. The chemical compositions of the complexes were confirmed by elemental analysis, and the structures and properties of them were discussed by IR, UV Vis, ESR, molar conductivities and solid conductivities.更多还原