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微乳液法纳米SnO2材料的合成、结构与气敏性能

Preparation, Microstructure and Gas Sensing Properties of Nanosized SnO2 Materials Made by Microemulsions

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【作者】 潘庆谊徐甲强刘宏民安春仙贾娜

【Author】 PAN Qing-Yi; XU Jia-Qiang; LIU Hong-Min; AN Chun-Xian; JIA Na(School of chemistry and Chemical enyineering, Shanghai University Shanghai 200072 China)(Department of Chemical Engineering, Zhe-on Institule of Light IndustryZhengzhou 150002 China)

【机构】 上海大学化学化工学院!上海200072郑州轻工业学院化学工程系!郑州450002

【摘要】 本文研究了由阴离子表面活性剂组成的微乳液在纳米SnO2气敏材料合成中的应用,研究了阴离子表面活性剂类型及肋表面活性剂对纳米SnO2材料平均晶粒度的影响.实验结果表明:由AES或K12和丁醇组成的微乳液可得到平均颗粒尺寸<20nm,平均晶粒度只有6nm左右的均分散SnO2,用这种材料制成的气敏元件无需掺杂即具有较高的气体灵敏度.

【Abstract】 The application of microemulsion made of anion surfactants in preparing SnO2 naosized materials was studied, and the influence of different anion surfactants and assistant surfactants onthe mean grain size of nanosized SnO2 was also researched by XRD and TEM. It can be knownfrom the experimental results, monodispersed SnO2 nanosized materials with the mean grain sizeo f about 6urn and average partical size smaller than 20um can be obtained from the microemulsion composed of AES or K12 anion surfactant and butanol assistant surfactant, and it has highsensitivity without catalysts and additives.

【基金】 河南省自然科学基金!954030500
  • 【文献出处】 无机材料学报 ,JOURNAL OF INORGANIC MATERIALS , 编辑部邮箱 ,1999年01期
  • 【分类号】TB381
  • 【被引频次】179
  • 【下载频次】867
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