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催化氢化硝基苯制备对氨基苯酚
SYNTHESIS OF p-AMINOPHENOL VIA HYDROGENATION OF MITROBENZENE OVER SUPPORTED PLATINUM CATALYSTS
【摘要】 研究了硝基苯催化加氢制备对氨基苯酚的反应。通过实验发现,不同的反应介质、添加剂、载体和催化剂的制备方法对对氨基苯酚的收率有很大的影响。在硫酸介质中两次性加入硝基本对反应最有利。AIBr3作添加剂时,可以提高目标产物的收率。改性的γ-Al2O3作载体时,对氨基苯酚的收率可达74%。
【Abstract】 The synthesis of para-aminophenol (PAP) from nitrobenzene isstudied by examining the effects of different reaction media, promoters,supports, and preparation methods of catalysts on the catalyst activity. Theresults show that tile aqueous solution of sulfuric acid is the most suitablereaction medium, A1Br3 is an effective promoter and Pt/modified γ-Al2O3 isa promising catalyst for this reaction.
【关键词】 硝基苯;
催化氢化;
对氨基苯酚;
铂催化剂;
【Key words】 nitrobenzene; catalytic hydrogenation; para-aminophenol; supported platinum catalyst;
【Key words】 nitrobenzene; catalytic hydrogenation; para-aminophenol; supported platinum catalyst;
- 【文献出处】 Journal of Natural Gas Chemistry ,天然气化学杂志(英文版) , 编辑部邮箱 ,1999年04期
- 【分类号】TQ243.1
- 【下载频次】149