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水溶性红曲黄色素的表征及其稳定性

CHARACTERIZATION AND STABILITIES OF WATER SOLUBLE MONASCUS YELLOW PIGMENT

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【作者】 苏金为周碧青彭时尧甘纯玑

【Author】 Su Jinwei,Zhou Biqing,Peng Shiyao,Gan Chunji (Fujian Agricultural University,Fuzhou 350002)

【机构】 福建农业大学!福州350002

【摘要】 以含硫化合物还原红曲色素,红斑素和红曲红素分子中的环羰基还原成羟基,得到水溶性红白曲黄色素.以 UV-Vis、IR和(?)H-13CNMR对其结构进行了表征.该色素的吸光度随pH增大而略呈上升趋势,避光可明显提高其稳定性.除Mg2+在pH9下使其溶液产生沉淀外,Sn2+、Ca2+、Fe3+和AI3+均不影响其稳定性.不同pH和温度下加热实验结果表明,酸性条件对其热稳定性影响较大.

【Abstract】 The water soluble Monascus yellow pigment was prepared by reducing the cyclocarbonyl of monascorubrin and rubropunctatin to hydroxyl with sulphuric compounds. Its structure was characterized by UV-Vis,lR and 1H-13C NMR. The absorbance of the pigment was increased slightly with pH. Taking shelter from the light would improve its stability. The stability was not effected by Sn2+,Ca2+, Fe3+,and A13+, while precipitation was produced by Mg2+ under pH 9. The acid effect was more than other conditions in thermal stability under different pH and temperature.

【基金】 福建省计划委员会资助项目
  • 【文献出处】 天然产物研究与开发 ,Natural Product Research and Development , 编辑部邮箱 ,1999年04期
  • 【分类号】O629
  • 【被引频次】12
  • 【下载频次】204
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