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后偶联高相对分子质量聚异丁烯基丁二酰亚胺分散剂
STUDY ON POST COULPED HIGH MOLECULAR WEIGHT POLYISOBUTENYL SUCCINIMIDE DISPERSANT
【摘要】 采用氯化烃化工艺和后偶联反应技术开发了一种氮含量高、热稳定性和氧化稳定性好的高相对分子质量的聚异丁烯基丁二酰亚胺分散剂。首先将聚异丁烯与马来酸酐在氯气存在下进行烃化,生成聚异丁烯基丁二酸酐;然后将烯酐与四乙烯五胺进行胺化。小试、中试和工业产品在MS程序ⅤD和ⅢD台架试验中都表现出良好的高/低温分散性能。
【Abstract】 A high molecular weight polyisobutenyl succinimide dispersant with high nitrogen content and good thermal and oxidative stabilities was developed. The preparation procedure was alkylation of polyisobutylene with succinic anhydride in the presence of chlorine to form polyisobutenyl succinic anhydride first, and was succeeded by the acylation reaction with tetraethylenepentamine. The products from laboratory, pilot plant and commercial test all showed good high/low temperature dispersity performance in MS sequence ⅤD and ⅢD engine tests.
【关键词】 高相对分子质量;
分散剂;
聚异丁烯;
偶联反应;
内燃机油;
【Key words】 high molecular weight; dispersing agent; polyisobutylene; coupling reaction; internal combustion engine oil;
【Key words】 high molecular weight; dispersing agent; polyisobutylene; coupling reaction; internal combustion engine oil;
- 【文献出处】 石油炼制与化工 ,PETROLEUM PROCESSING AND PETROCHEMICALS , 编辑部邮箱 ,1999年03期
- 【分类号】TQ323.7
- 【被引频次】7
- 【下载频次】193