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环戊二烯催化甲基化制备甲基环戊二烯催化剂筛选及制备条件的研究

Research on Screening and Preparing of Catalyst Used for Catalystic Methylation of Cyclopentadiene to Prepare Methylcyclopentadiene

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【作者】 郑丹龚真固赵鸣玉

【Author】 Zheng Dan\ Gong Zhengu\ Zhao Ming yu (Department of Fine Chemical Technology,Shengyang Institute of Chemical Technology,Shengyang 110021,China)

【机构】 沈阳化工学院精细化工系

【摘要】 从反应系统的特点考虑,选定了几种具有不同酸碱特性的金属氧化物进行复配处理,在一定条件下进行相应的催化活性试验,并利用正交试验,确定了制备催化剂的最佳工艺条件。结果表明:以95%及无水乙醇混合制备的Al2O3MgOK2CO3三组分催化剂具有适合的酸、碱中心,是环戊二烯与甲醇催化甲基化合适的催化剂。这种催化剂制备最佳工艺条件为:摩尔比3∶2∶1,焙烧温度700℃,焙烧时间6h。

【Abstract】 In this artical, considering the characteristic of reaction system ,we select some metal-oxids which have different acid-base properties to make up, and test their catalystic activities in a define condition. According to the orthographical design, the best production conditions prepared the catalyst were determinded. It’s shown that the catalyst prepared from Al 2O 3 with supported MgO and K 2CO 3 mixed in 95% or 100% ethyl alcohol has suitable acid-base center, and it is the suitable catalyst to methylation of cyclopentadiene and methanol. The best production conditions prepared the catalyst were: the mole proportion of catalystic components is Al 2O 3∶MgO∶K 2CO 3=3∶2∶1, the calcining termperature is 700℃,calcining time is 6h.

  • 【文献出处】 沈阳化工 ,SHENYANG CHEMICAL INDUSTRY , 编辑部邮箱 ,1999年01期
  • 【分类号】TQ231.22
  • 【下载频次】85
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