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用混合C5馏份制甲基异丙基酮
Preparation of Methyl Isopropyl Ketone from Mixed C_ 5 Fractions
【摘要】 以混合C5 馏份为原料,用自制硅藻土- 磷酸作催化剂,经水合制备甲基异丙基酮。试验表明,在催化剂的浸酸质量分数为65 % 、反应温度220 ℃、n( 水) n(C5) = 6 .2 、LHSV 为0-32 h - 1 时,甲基异丙基酮的收率为66 % ,选择性为83 % ,异戊二烯的转化率为80 % 。
【Abstract】 Methyl isopropyl ketone was prepared from mixed C 5 fractions by hydration with self-made diatomaceous earth supported phosphoric acid as catalyst.Under the conditions of phosphoric acid concentration of 65%,reaction temperature of 220 ℃,n(water)∶n(C 5)=6.2,and LHSV of 0.32 h -1 , the yield of methyl isopropyl ketone reaches 66%,with a selectivity of 83% and an isoprene conversion of 80%.
- 【文献出处】 石油化工 ,PETROCHEMICAL TECHNOLOGY , 编辑部邮箱 ,1999年11期
- 【分类号】TQ413.24
- 【被引频次】8
- 【下载频次】143