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不同金属离子对氧化铝再水合性质的影响
INFLUENCE OF DIFFERENT METAL IONS ON THE REHYDRATION PROPERTIES OF ALUMINAS
【摘要】 用XRD方法考察了以浸渍法负载不同金属离子后,这些离子对γ-Al2O3 载体在130℃,22h 水热及自生压力条件下再水合性质的影响。按氧化铝水合物转化率由大到小的顺序排列, 得到以下结果: K+ > Ca2+ >Fe3+ > Zr4+ > Cu2+ > Ni2+ > Mg2+ > Li+ > Co2+ , Ce3+ , Zn2+ 。
【Abstract】 The influence of different metal ions on rehydration properties of γ Al 2O 3 supports was investigated through XRD after various metal ions were added by the impregnation method The rehydration process was accomplished under saturated vapor pressure at 130℃ for 22h The sequence of the conversion,from high to low,of alumina hydrate was K +>Ca 2+ >Fe 3+ >Zr 4+ >Cu 2+ >Ni 2+ >Mg 2+ >Li +>Co 2+ ,Ce 3+ ,Zn 2+ .
【关键词】 氧化铝;
再水合;
金属离子;
水热稳定性;
负载型催化剂;
【Key words】 alumina; rehydration; metal ion; hydrothermal stabilization; supported catalysts;
【Key words】 alumina; rehydration; metal ion; hydrothermal stabilization; supported catalysts;
- 【文献出处】 石油学报(石油加工) ,ACTA PETROLEI SINICA (PETROLEUM PROCESSING SECTION) , 编辑部邮箱 ,1999年05期
- 【分类号】O643.36
- 【被引频次】27
- 【下载频次】284