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鸭儿湖地区六氯环己烷的残留动态与长期归宿

DYNAMICS AND LONG-TERM FATE OF RESIDUAL HEXACHLOROCYCLOHEXANE (HCH) IN VARIOUS TYPES OF ENVIRONMENT IN YA-ER LAKE AREA, CHINA

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【作者】 徐盈吴文忠张银华张甬元Kettrep A

【Author】 Xu Ying;Wu Wenzhong;Zhang Yinhna;Zhang Yongyuan(Institute of Hydrobiology, The Chinese Academy of Sciences, Wuhan 430072)A. Kettrup(Institute of Ecological Chemistry/ GSF, Neuherberg D-85764, Germany)

【机构】 中国科学院水生生物研究所!武汉430072德国环境与健康研究中心生态化学研究所

【摘要】 在1990—1993年期间,研究了历史上曾被HCH严重污染的鸭儿湖地区的水生态系统和陆生生态系统中HCH的残留动态与归宿,获得了HCH在各种不同环境条件下的残留动态方程与环境半衰期.结果表明:鸭儿湖底泥是HCH长期残留的主要归宿。尽管HCH已禁用十几年,目前该地区环境中HCH的残留已降至亚ng/g级水平,然而它在淡水食物链中仍然存在很高的生物积累.残留的HCH在各种环境中的分布和转移均与该地区有机质含量呈正相关。目前环境中HCH残留的主要异构体是β-HCH。同时各种环境中HCH的残留动态可用指数方程来表示,其半衰期在四种不同环境中的顺序为:水<土壤<稻田泥<底泥。

【Abstract】 A study on dynamics and long-term fate of residual hexachlorocyclohexane(HCH)in aquatic and terrestrial environments in Ya-Er Lake Area,heavily pollutedby HCH historically, was carried out during the period from 1990-1993. Theconcentration Kinetics and half-lived bine of HCH-residues in four differentenvironments were obtained. The results show that sediment is the primaryaccumulation site for the long-term fate of HCH--residues. Despite HCH was bannedfor more than ten years in Ya-Er Lake Area,the bioaccumulation of HCH-residue infreshwater food chain was still high (BCF=104 in fish liver). The distribution andmobility of HCH-residues are correlated with the organic matter positively. TheHCH-residue in the current environmentin that area is mainlyβ-HCH. Meanwhile, aseries of model exponential equations are used for describing dynamics ofHCH-residues. From these equations, the half-lived time calculated and the order infour different environments are:water < soil < mud of paddy field < sediment.

【关键词】 残留动态长期归宿六氯环己烷
【Key words】 DynamicsLong-termFateHexachorocyclohexane
【基金】 德国VW科学基金;淡水生态与生物技术国家重点实验室基金
  • 【文献出处】 水生生物学报 ,ACTA HYDROBIOLOGICA SINICA , 编辑部邮箱 ,1999年04期
  • 【分类号】X13
  • 【被引频次】23
  • 【下载频次】139
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