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非离子型微乳液增敏光度法的研究——OP微乳液-Fe-PV光度体系
Spectrophotometric Study on the Fe PV System Enhanced by Nonionie Microemulsion
【摘要】 研究了以非离子型乳化剂OP与正戊醇、正庚烷、水四组分构成的微乳液为介质,铁与邻苯酚紫的显色体系.在给定条件下,该显色体系的ε614=6.44×104L/mol·cm,与以水为介质和乳化剂OP胶束为介质比较,灵敏度显著增加,且最大吸收波长也分别向长波方向移动
【Abstract】 The effect of microemulsion,OP/n C 5H 11 OH/n C 7H 16 /H 2O as a medium of Fe(Ⅲ) PV complex is studied.The apparent molar absorptivity is 6 44×10 4 L·mol -1 ·cm -1 at 614nm,Beers law is obeyed in the range of 0 ̄2 mg/L for Fe(Ⅲ).This method is applied to the determination of Fe in water.The results is satisfactory. [
【关键词】 铁;
邻苯二酚紫;
微乳液;
分光光度法;
【Key words】 iron; pyrocatechol violet; microemulsion; spectrophotometry.;
【Key words】 iron; pyrocatechol violet; microemulsion; spectrophotometry.;
- 【文献出处】 沈阳工业学院学报 ,JOURNAL OF SHENYANG INSTITUTE OF TECHNDOGY , 编辑部邮箱 ,1999年01期
- 【分类号】O657.3
- 【被引频次】1
- 【下载频次】40