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5-(4-磺基-1-萘偶氮)-8-羟基喹啉离解常数及其与镱显色反应分光光度法的研究
Spectrophotometric Studies on the Constant of Dissociation on 5-(4-Sulfo-1-Naphthy Lazo)-8-Hydroxy Quinoline and Its Chromogenic Reaction with Ytterbium
【摘要】 本文用分光光度法测定了显色剂5-(4-磺基-1-萘偶氮)-8-羟基喹啉离解常数,并研究了该显色剂与Yb的络合情况.结果表明:在pH为2-12之间,该显色剂共有三种存在形式:H2L(NH+)、HL-、L2-,它的离解常数为Ka1=1.61×10-5,Ka2=4.10×10-9.在pH=9.60附近,该显色剂可与Yb3+形成3:1、2:1、1:1的配合物.
【Abstract】 A Spectrophotometric method has been used to study the constant of dissociation on 5-(4-sulfo-1-naphthy lazo)-8-hydroxy quinoline and its chromogenic reaction with Ytterbium at pH = 2-12. In the experimental conditions, the chromogenic reagent has three shapes: H2L(NH- ) , HL-, L2-, its constant of dissociation is: Ka1 =1. 61 X 10-5, Ka2 =4. 1 X 10-9. At pH= 9. 6 nearby, it reacts with Ytterbium to form 3: 1, 2: 1, 1: 1 complex.
- 【文献出处】 山西师范大学学报(自然科学版) ,THE JOURNAL OF SHANXI TEACHERS UNIVERSITY(NATURAL SCIENCE EDITION) , 编辑部邮箱 ,1999年03期
- 【分类号】O657.3
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