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铜含量对Cu/ZrO2和Cu-La2O3/ZrO2催化剂性能影响

EFFECT OF COPPER CONTENT ON PERFORMANCE OF Cu/ZrO2 AND Cu-La2O3/ZrO2

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【作者】 吴贵升任杰孙予罕

【Author】 Wu Guisheng Ren Jie Sun Yuhan (State Key Laboratory of Coal Conversion Institute of Coal Chemistry Chinese Academy of Sciences Taiyuan)

【机构】 中国科学院山西煤炭化学研究所煤转化国家重点实验室!太原030001

【摘要】 本文考察了铜含量对CuZrO2和Cu-La2O3ZrO2催化剂性能影响。结果表明,当铜含量较低时,铜在催化剂中以高分散状态存在,并随铜含量增加,催化剂活性线性增加。当铜含量超过某一值,部分铜组分以体相铜形式存在,催化剂活性随铜含量变化不明显。因此,高分散铜为影响CuZrO2催化剂活性主要因素。

【Abstract】 The Cu/ZrO 2 and Cu-La 2O 3/ZrO 2 catalysts with different copper content were investigated in the present work The copper in the catalysts with lower copper loading was in a highly-dispersed state and the activity of catalysts was then linearly enhanced with the rise of copper content Parts of copper formed into bulk CuO as its content was up to a certain value, but the activity of catalysts showed hardly change with the rise of copper content Hence, highly-dispersed copper was considered to be responsible for the activity of Cu/ZrO 2 catalysts

【关键词】 CuZrO2Cu-La2O3/ZrO2铜含量
【Key words】 Cu/ZrO 2Cu-La 2O 3/ZrO 2copper content
【基金】 国家自然科学基金!资助项目 ( 2 98730 64 )
  • 【文献出处】 燃料化学学报 ,JOURNAL OF FUEL CHEMISTRY AND TECHNOLOGY , 编辑部邮箱 ,1999年06期
  • 【分类号】O643.36
  • 【被引频次】11
  • 【下载频次】102
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