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聚氨酯改性聚丙烯酸类填充树脂的研究
Study on Filling Resin(JPU) of Polyacrylic AcidModified with Polyurethane
【摘要】 将聚醚1、甲苯二异氰酸酯(TDI)投入反应瓶中,并在较低温度下,预聚反应1~2h,然后将具有较好流动性未反应完的PU预聚体加入到聚醚2和有机酸酐半脂反应瓶中,继续进行多段共聚反应,制得改性聚氨酯(PU)溶液;然后在有机胺碱性条件下,用非离子型乳化剂进行乳化,合成出改性聚氨酯(PU)乳液。PU乳液与PA填充树脂,在一定条件下,共混合成聚氨酯改性聚丙烯酸(简称JPU)填充树脂
【Abstract】 Put polyether 1,TDI(Toluene Diisocynate) into a react flask,kept pre_polymerizing at lower temp. for 1h,then the above_prepolymer of incompletely reacted PU with good flowability was added into another flask containing polyether 2 and anhydride of organic acid to continue multistage copolymerizing to obtain a modified PU solution,and followed by emulsifying the above PU solution with nonionic emulsifying agent in the presence of organic amine to obtain a modified PU emulsion. PU emulsion was mixed with PA filling resin to obtain a PU emulsion_modified PA filling resin (JPU filling resin,hereafter).
【Key words】 PU_modified PA emulsion; filling resin for leather; nonionic polymers;
- 【文献出处】 皮革化工 ,LEATHER CHEMICALS , 编辑部邮箱 ,1999年03期
- 【分类号】TQ323.8,TQ323.8
- 【下载频次】121