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改性丙烯酸树脂皮革涂饰剂研制

Preparation of Modified Acrylic Resin Finishing Agent

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【作者】 武文洁张学安郭海涛汤琦黄汉昌

【Author】 WU Wen_jie,ZHANG Xue_an,GUO Hai_tao,TANG Qi,HUANG Han_chang(Department of Chemical Engineering,Tianjin Institute of Light Industry, Tianjin 300222,China)

【机构】 天津轻工业学院化工系!天津300222

【摘要】 以丙烯酸丁酯为软单体,以丙烯腈和苯乙烯为硬单体,加入丙烯酸和N羟甲基丙烯酰胺改性剂通过半连续乳液聚合法合成了改性丙烯酸树脂皮革涂饰剂,并讨论了影响乳液性能的一些因素。

【Abstract】 The emulsion polymerization reaction is carried out in a 4_mouth flask with stirrer, thermometer, reflux condenser and constent titration funnel. The total component contents are 36%-40%, including styrene 3%-5%, acrytlic acid 1%-2%, N_hydroxymethyl acrylamide 2%-3%, compound emulsifier 2%-3%, and ammonium persulfate as primer 0.25%. All the components are added in the form of semi_continued procedure, while the addition of styrene is late in the reaction. The emulsion polymerization time and temperature_keeping time are 2.5h and 1h, separately, and the reaction temperature is 85℃.

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