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芳氧苯氧丙酸酯和环己二酮类除草剂的作用机制

The Mechanisms of Action of APP and CHD Herbicides

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【作者】 任康太; 李永红; 杨华铮;

【Author】 Ren Kangtai et al. (Institute of Elemento-Organic Chemistry,Nankai University,Tianjin 300071)

【机构】 南开大学元素有机化学研究所;

【摘要】 报道了两类除草剂芳氧苯氧丙酸酯(APP)和环己二酮(CHD)的四种主要的除草作用机制。其中,ACC酶是它们公认的作用靶标;膜电位去极化是目前仍在争议中的作用机制;三酮类CHD能够抑制HPPD酶的活性;肟醚类CHD则可作为光电子传递抑制剂。文中还介绍了基于ACC酶设计的新抑制剂。

【Abstract】 Four main mechanisms of the action of aryloxyphenoxypropionate (APP)and cyclohexanedione(CHD)herbicides have been reported.There is strong evidence that they inhibit ACCase,a key enzyme that catalyzes the first committed step in de novo biosynthesis of fatty acids.The depolarization of Em is a controversial mode.CHD with a benzoyl group could inhibit plant HPPDase,a component of the biosynthetic pathway to plastoquinone and α-tocopherol,while CHD with an enamine moiety are potent electron transport inhibitors.The design of novel graminicides based on ACCase is introduced.

  • 【分类号】TQ457.011
  • 【被引频次】35
  • 【下载频次】507
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