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呼和浩特市大气颗粒物中几种多环芳烃的粒度分布

The Distribution of Some Polycyclic Aromatic Hydrocarbons in the Atmosphere Particulates

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【作者】 冯沈迎阮玉英仝青赵天骄杨芳

【Author】 FENG Shen ying,RUAN Yu ying,TONG Qing,ZHAO Tian jiao,YANG Fang (NeiMongol Environmental Monitoring Center,Hohhot 010010,PRC)

【机构】 内蒙古环境监测中心站

【摘要】 将五段多孔冲击分级器(粒径分级:<1.1,1.1~2.0,2.0~3.3,3.3~7.0,>7.0μm)与大流量采样器连接,于1996年冬夏两季采集呼和浩特市居民区、交通区、对照区(较清洁区)大气中的颗粒物,用高压液相色谱仪(HPLC)测定样品中的菲(PHEN)、蒽(ANTH)、芘(PYRE)、苯并〔a〕蒽(BaA),艹屈(CHRY)、苯并〔a〕芘(BaP)等六种多环芳烃化合物(PAHs).数据表明:①这六种PAHs在颗粒物中的质量中值直径(MMD),冬夏季均小于1μm;PAHs含量冬季平均有98.5%,夏季有95.5%富集在小于7μm的可吸入颗粒中;②以(质量/体积)浓度比较,冬季居民区、交通区、对照区的PAHs平均值分别高于夏季80倍,30倍和18倍,呈典型的煤烟型污染的季节差异特征.三区浓度比较,冬夏季均居民区>交通区>对照区;③以(质量/体积)浓度累积百分数比较,三区7μm以下各级颗粒物中PAHs的富集度,冬夏季大多是交通区>居民区>对照区,即由于汽车尾气污染,交通区大气中的PAHs在小颗粒上的富集度相对更高些

【Abstract】 The atmospheric particulates were collected in the residential area and the traffic area and the control area (the better clean area) in winter and summer using a five laminated multiple divisible impacted (the diameters of particulates are as follows:<1.1,1.1 ̄2.0,2.0 ̄3.3,3.3 ̄7.0, >7.0 μm connected with a big flow collecting sampler.The six kinds of polycylic aromatic hydrocarbons (PAH s) in the sample,that is Phen,Anth,Pyer,BaA,Chry and BaP,were detected by using HPLC.The follow results were obtained:1.The MMDs of these six PAH s in the particulates were all less 1 μm in winter and summer.The content of PAH s enriched in particulates which the diameters were less than 7 μm and can be inhaled was aboue 98.5% in winter and 95.5% in summer.2.Comparing with the concentration in mass/volume,the mean values of PAH s in winter were 80 times in the residential area,30 thimes in the traffic area and 18 times in the control area higher than in summer respectively,which was typical character of the pollution by coal smoke in different season.Comparing the concentration these three areas,the results in winter and summer were all that the residential area >the traffic area>the control area.3.Comparing with the percentage of the cumulative concentration in mass/volume,in these three areas the enriched degree of PAH s in the particulates which the diameters were less 7 μm is all that:the traffic area>the residential area>the control area in winter and summer,that is,because of the pollution of the automobile tail gas the enriched degree of PAH s in fine particulates in the traffic area was relatively high.

【基金】 内蒙古科委攻关计划项目基金
  • 【文献出处】 内蒙古大学学报(自然科学版) ,ACTA SCIENTIARUM NATURALIUM UNIVERSITATIS NEIMONGOL , 编辑部邮箱 ,1999年04期
  • 【分类号】X831
  • 【被引频次】17
  • 【下载频次】111
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