【摘要】 用纤维素二苯基膦与PdC12制备了纤维素膦-钯催化剂，在纤维素膦-钯催化剂上对空间位阻大的2-亚环戊基环戊酮的烯键催化氢化进行了研究．利用气相色谱法测定了催化氢化反应的反应程度及选择性．探讨了2-亚环戊基环戊酮在纤维素膦-钯催化剂上合成2-亚环戊基环戊酮的反应机理．更多还原

【Abstract】 Catalyst of palladium complexes with cellulose diphenyl phasphine had been prepared Bypalladium chloride and cellulose diphenyl phasphine. Hydrogenation of 2- cyclopentylidene cyclopentanone that is stereoacopically defined had been studied. Reactivity and selectivity of hydrogenation reaction were determined by GC. The mechanism of hydrogenation of cyclopentylidene cyclopentanone were dilcussed.更多还原