【摘要】 目的：研究CU（Ⅰ）催化及相转移条件下，末端烯（炔）丙基化偶联反应。方法：通过Cu（Ⅰ）催化及相转移催化反应合成十四个目标化合物，并用XRC－1显微熔点仪，Abbe’折光仪，FI-IR170SX光谱法，Finnigan－MAT4510型CC/MS色谱法，FX-90Q1HNMR光谱法对目标化合物进行检测。结果：本文合成反应条件温和稳定，催化剂用量少，收率高，区域选择性好。结论：1，4-烯炔，1，4-二炔是合成国槐尺蠖昆虫信息素组份的主要砌块，本研究对实现国槐尺蠖昆虫信息素合成有重要意义。更多还原

【Abstract】 Objective : To study the allylic or propargylic coupling reaction of terminal alkyne under copper (Ⅰ)catalysis and Phase transfer condition. Methods: 14 destined compounds were synthesized by copper (Ⅰ) catalysis andPhase transfer catalytic reaction and were surveyed and appraised by meens of XRC -1 microscopic meting point meter ,Abbe refractometer, FI -IR170SX spectroscopy, Finingan - MAT4510 GC/MS chromatography , and FX - 90QHNMR spectroscopy . Results: The condition of synthetic reaction is soft and stable, dose of catalyst is minimal,proportion of reclaim superior, regioselectivity good. Conclusion: 1, 4 - Alkene or Alkyne 1, 4 - Diine are importantbuilding block for synthesizing Macaria Eiongaria Leech insect sex Pheromone. The new synthetic methodology has im-portant significance to achieve the synthesis of Macaria Eiongaria Leech Insect sex pheromone.更多还原