节点文献
常压CO2气流法制D,L-丙交酯
Preparation of Lactide from Lactic Acid at Normal Pressure \= by the CO\-2 Flow Process
【摘要】 在CO2气流中用D,L乳酸为原料,硫酸亚锡为催化剂,包括内外消旋体的粗丙交酯产率可达82%,外消旋D,L丙交酯约占其中的1/2。作为对比,用N2气流时的粗丙交酯产率为83.2%,二者产率相差无几,可用CO2代替N2用于丙交酯的制备
【Abstract】 Lactide was prepared in the CO\-2 flow starting from lactic acid and using stannous sulfate as catalyst.The yield of raw lactide including the racemic and meso isomers could reach 82% versus a yield of 83.2% in the N\-2 flow.The racemic D,L lactide accounted for about half of the yield.The results were very close to CO\-2 and N\-2 used,suggesting that CO\-2 can replace N\-2 in lactide producing process.\=
【关键词】 丙交酯;
二氧化碳;
乳酸;
【Key words】 lactide; CO\-2; lactic acid\= Foundation item: Granted by state natural science fund (29464011); supported by Guangxi science committee fund(9543004);
【Key words】 lactide; CO\-2; lactic acid\= Foundation item: Granted by state natural science fund (29464011); supported by Guangxi science committee fund(9543004);
【基金】 国家自然科学基金,广西科委匹配资金项目
- 【文献出处】 精细化工 ,FINE CHEMICALS , 编辑部邮箱 ,1999年03期
- 【分类号】TQ324.9
- 【被引频次】40
- 【下载频次】130