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常压CO2气流法制D,L-丙交酯

Preparation of Lactide from Lactic Acid at Normal Pressure \= by the CO\-2 Flow Process

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【作者】 苏涛覃玉莹马华韦磊

【Author】 SU Tao,QIN Yuying,MA Hua,WEI Lei\= (College of Chemistry and Chemical Engineering,Guangxi University,Nanning 530004,China)\=\=

【机构】 广西大学化学化工学院化学系

【摘要】 在CO2气流中用D,L乳酸为原料,硫酸亚锡为催化剂,包括内外消旋体的粗丙交酯产率可达82%,外消旋D,L丙交酯约占其中的1/2。作为对比,用N2气流时的粗丙交酯产率为83.2%,二者产率相差无几,可用CO2代替N2用于丙交酯的制备

【Abstract】 Lactide was prepared in the CO\-2 flow starting from lactic acid and using stannous sulfate as catalyst.The yield of raw lactide including the racemic and meso isomers could reach 82% versus a yield of 83.2% in the N\-2 flow.The racemic D,L lactide accounted for about half of the yield.The results were very close to CO\-2 and N\-2 used,suggesting that CO\-2 can replace N\-2 in lactide producing process.\=

【基金】 国家自然科学基金,广西科委匹配资金项目
  • 【分类号】TQ324.9
  • 【被引频次】40
  • 【下载频次】130
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