【摘要】 利用改进的Ｒｏｓｅ－Ｗｉｌｉａｍｓ平衡釜测定了氯代叔丁烷－叔丁醇体系在０１０１３ＭＰａ下的汽液平衡数据，实验数据通过了热力学一致性检验。分别用Ｗｉｌｓｏｎ、ＮＲＴＬ和ＵＮＩＱＵＡＣ三种活度系数模型对实验数据进行关联，采用单纯形法来回归方程参数，关联结果和实验数据吻合良好。更多还原

【Abstract】 The isobaric vapor-liquid equilibrium data of 2-chloro-2-methylpropane (1) and tert-butyl alcohol(2) system are measured at 0101 3 MPa by using modified Rose-Williams still The experimental data are tested for thermodynamic consistency and correlated satisfactorily with three thermodynamic models: WilsonNRTL and UNIQUAC activity coefficient equations The parameter of three models for the binary system are related by the simplex method The calculated values are in agreement with the experimental data更多还原