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12-钨磷杂多酸及其Ce(Ⅲ)、A1(Ⅲ)难溶盐催化合成肉桂酸异戊酯

Study on synthesis of isopentyl cinnamate catalyzed by 12-tungstophosphoric acid and its sparingly soluble Ce(III ),AI(III) salts

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【作者】 庞先杰; 钟邦克;

【Author】 PANG Xian -jie; ZHONG Bang - ke (Dept. of Chemistry, Jinan University, Guangzhou 510632, China)

【机构】 暨南大学化学系!广东广州510632;

【摘要】 用12-钨磷杂多酸及其Ce(Ⅲ)、A1(Ⅲ)盐为催化剂合成肉桂酸异戊酯,工艺简单,缩短了反应时间(耗时不超过2h),催化剂首次使用的酯收率在95%以上,难溶盐催化剂可多次重复使用,可降低催化剂的消耗和腐蚀.

【Abstract】 Isopentyl cinnamate was synthesized by using PW12 heteroply acids and its springly solubleCe(III ), AI(III ) salts as catalyst. The reaction take was reduced. It was 2 h. Yields of the ester were> 95% for catalysts used for the first time. The technological process is simple and these sparing solublesalts can be reused as catalyst for many times. It is possible to decrease the comsumption and the corrosion behavior of catalysts.

  • 【文献出处】 暨南大学学报(自然科学与医学版) ,Journal of Jinan University(Natural Science & Medicine Edition) , 编辑部邮箱 ,1999年03期
  • 【分类号】O643.3
  • 【被引频次】1
  • 【下载频次】53
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