【摘要】 采用元素分析、Ｘ射线光电子谱（ＸＰＳ）以及直流电导率σｄｃ（Ｔ）与温度关系等方法对三种聚苯胺ＰＡＮＩ－ＨＣｌ，ＰＡＮＩ－Ｈ２ＳＯ４和ＰＡＮＩ－Ｈ３ＰＯ４进行了研究．在Ｃｌ（２ｐ）谱中，可以分辨四个二重态的自旋轨道裂分偶极子Ｃｌ（２ｐ１／２）和Ｃｌ（２ｐ３／２）．Ｓ（２ｐ）－ｃｏｒｅ－ｌｅｖｅｌ谱显示了二重态自旋轨道的裂分偶极子Ｓ（２ｐ１／２）和Ｓ（２ｐ３／２），而Ｐ（２ｐ）－ｃｏｒｅ－ｌｅｖｅｌ谱仅在结合能为１３４．０３ｅＶ时显示单一的峰值．室温时ＰＡＮＩ－ＨＣｌ和ＰＡＮＩ－Ｈ２ＳＯ４的σｄｃ比ＰＡＮＩ－Ｈ３ＰＯ４的σｄｃ高数倍．ＰＡＮＩ样品的导电性与温度的关系表明它们是半导体，而且符合准一维的变程跳跃（Ｑ１Ｄ－ＶＲＨ）模型更多还原

【Abstract】 A comparative study among three kinds of polyaniline, PANI HCl, PANI H 2SO 4 and PANI H 3PO 4 were reported. The elemental analysis, X ray photoelectron spectroscopy (XPS) and temperature dependence of dc conductivity σ dc (T) were carried out. In the Cl(2p) spectrum, four spin orbit split doublets Cl(2p 1/2 ) and Cl(2p 3/2 ) were resolvable. The S(2p) core level spectrum showed two spin orbit split doublets S(2p 1/2 ) and S(2p 3/2 ), and P(2p) core level spectrum exhibits only a single peak with binding energy of 134.03eV. At the room temperature σ dc of PANI HCl and PANI H 2SO 4 were several times higher than that of PANI H 3PO 4. The temperature dependence conductivity of our different PANI samples showed a semiconductor behavior, and it follows the quasi one dimensional variable range hopping (Q1D VRH) model.更多还原