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薄层色谱在有机物顺反及对映异构体分离中的应用

METHODS FOR SEPARATING ISOMERS AND OPTICAL EANATIOMERS USING LAYER CHROMATOGRAPHY

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【作者】 陈晓; 龙韫先; 邓峰杰;

【Author】 Chen Xiao;Long Yun-Xian(Research institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071)Deng Feng-Jie(Chemistry Dept., Nanchang University, Nanchang 330047)

【机构】 南开大学元素所!天津300071; 南昌大学化学系!南昌330047;

【Abstract】 Methods for separating 1-(2,4-Dichlorophenyl) 4, 4-dimethyl 1-2(1,2,4-triazol-l-yl) 1-penten-3-ol isomers and D,L-tryptophan enantiomers using HPTLC and TLC were investigated. The effects on Separation made by different nonchiral mobile phase, chiral mobile phase and two different shapes of plates were studied. Useful separation was obtained forstereoisomers, and the resolution of D, L-tryptophan was good by using chiral mobile phase additive(D-quinia).

  • 【文献出处】 化学研究与应用 ,CHEMICAL RESEARCH AND APPLICATION , 编辑部邮箱 ,1999年05期
  • 【分类号】O657.7
  • 【被引频次】9
  • 【下载频次】282
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