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薄层色谱在有机物顺反及对映异构体分离中的应用
METHODS FOR SEPARATING ISOMERS AND OPTICAL EANATIOMERS USING LAYER CHROMATOGRAPHY
【Abstract】 Methods for separating 1-(2,4-Dichlorophenyl) 4, 4-dimethyl 1-2(1,2,4-triazol-l-yl) 1-penten-3-ol isomers and D,L-tryptophan enantiomers using HPTLC and TLC were investigated. The effects on Separation made by different nonchiral mobile phase, chiral mobile phase and two different shapes of plates were studied. Useful separation was obtained forstereoisomers, and the resolution of D, L-tryptophan was good by using chiral mobile phase additive(D-quinia).
【关键词】 薄层色谱;
环糊精;
光学异构体;
手性流动相;
【Key words】 thin layer chromatography; cyclodextrin; optical isomer; chiral mobile phase;
【Key words】 thin layer chromatography; cyclodextrin; optical isomer; chiral mobile phase;
- 【文献出处】 化学研究与应用 ,CHEMICAL RESEARCH AND APPLICATION , 编辑部邮箱 ,1999年05期
- 【分类号】O657.7
- 【被引频次】9
- 【下载频次】282