节点文献
[Co（p-Me-PPA）2,（H2O）2]Cl的合成及其催化环己烯氧化反应的研究
STUDY ON SYNTHESIS OF COMPLEX [Co（p-Me-PPA）2（H2O）2]Cl AND CATALYTIC OXIDATION OF CYCLOHEXENE
【Abstract】 Complex Cobalt(III) di[N-(p-methyl)phenyl-2 -pyridinecarboxamide] dihydrate chloride [Co(p-Me-PPA)2(H2O)2] Cl hadbeen synthesised. The single crystal strUcture of the metal complex had been successfully prepared and determined by fourcircle single crystal diffractometer. When the oxidation of cyclohexene was catalyzed by [Co(p-Me-PPA)2(H2O)2]Cl withmolecular oxygen as oxidant, the conversion reached 59% , the selectivity of cyclohexenone being 75%.
【关键词】 吡啶甲酰胺配体；
钴配合物；
环己烯；
氧；
催化氧化；
【Key words】 pyridinecarboxamide ligand； cobalt complex single crystal； cyclohexene； O2； catalyticoxidation；
【Key words】 pyridinecarboxamide ligand； cobalt complex single crystal； cyclohexene； O2； catalyticoxidation；
- 【文献出处】 化学研究与应用 ,CHEMICAL RESEARCH AND APPLICATION , 编辑部邮箱 ,1999年05期
- 【分类号】O624.12
- 【被引频次】16
- 【下载频次】81