节点文献
新型季铵盐阳离子表面活性剂的合成及结构表征
Synthesis and Characterization of New Quaternary Ammonium Salt Cationic Surfactants
【摘要】 以聚氧乙烯脂肪醇和环氧氯丙烷在相转移催化条件下反应,高收率得到聚氧乙烯脂肪醇缩水甘油醚,以此为原料和三甲胺盐酸盐反应定量得到N-[3-单(双)氧乙烯长链烷氧-2-羟]丙基-N,N,N-三甲基氯化铵,通过元素分析,红外光谱和核磁共振氢谱对其结构进行了鉴定。
【Abstract】 N [3 Alkylmono(di) oxyethylene oxy 2 hydroxy] propyl N,N,N trimethylammonium chloride,were synthesized from trimethylammonium chloride and polyoxyethylene fatty alcohol glycidylethers which were prepared at high yield by phase transfer catalyzed synthesis of polyoxyethylene fatty alcohol and epichlorohydrin.Their structures were confirmed by IR, 1HNMR Spectra and elemental analysis.
【关键词】 脂肪醇;
环氧氯丙烷;
三甲胺;
季铵盐;
【Key words】 fatty alcohol epichlorohydrin trimethylamine quaternary ammonium salt;
【Key words】 fatty alcohol epichlorohydrin trimethylamine quaternary ammonium salt;
【基金】 山东省自然科学基金
- 【文献出处】 化学世界 ,HUAXUE SHIJIE (CHEMICAL WORLD) , 编辑部邮箱 ,1999年02期
- 【分类号】TQ423.121
- 【被引频次】24
- 【下载频次】635