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乙烯催化氧乙酰化反应研究 Ⅱ 催化反应器的数学模拟和优化计算

THE STUDIES OF VINYL ACETATE SYNTHESIS BY VAPOR PHASE ACETOXYLATION OF ETHYLENE MATHEMATICAL MODEL AND OPTIMUM CALCULATION OF CATALYSIS REACTOR

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【作者】 谢雪英; 高清山; 王尚弟;

【Author】 XIE Xueying , GAO Qingshan , WANG Shangdi(United Chemical Reaction Engineering Institution Zhejiang University, Hangzhou 310027, China)

【机构】 浙江大学联合化学反应工程研究所;

【摘要】 借助于已测得的乙酸乙烯催化剂动力学方程,对工业反应器进行了二维数学模拟分析,在不同条件下对反应器床层内温度及转化率进行了预测。结果表明在现工业条件下催化剂运转是安全的,并有较大操作弹性;同时还预测了造成飞温的条件

【Abstract】 With the kinetics of two new kinds vinyl acetate catalysts CTV and KRV proposed previausly, a twodimensional mathematical model was proposed in use of analysing a induslrial reactor. At different conditions, the temperature distribution and conversion content in the reactor was simulated. The results showed that it was safty to use the two new kinds of catalysts at industrial operating conditions, and can be run in a wide operation range. At the same time, the conditions of causing uncontrolled temperature was predicted.

【关键词】 乙酸乙烯; 催化剂; 数学模拟;
【Key words】 vinyl acetate; catalyst; model;
  • 【文献出处】 化学反应工程与工艺 ,CHEMICAL REACTION ENGINEERING AND TECHNOLOGY , 编辑部邮箱 ,1999年02期
  • 【分类号】TQ018
  • 【下载频次】119
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