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硫酸钴中铁的测定──萃取分离原子吸收光谱法
Determination of Iron in Cobalt Sulfate-Extration Separation and Atomic Absorption
【摘要】 硫酸钴中铁的测定主要问题是存在钴基体对测定方法严重干扰。本文提出了在约7mol/L盐酸介质中,用乙酸乙酯萃取与钴分离,然后用水反萃取,在(1+19)的盐酸介质中,以空气-乙炔火焰,于原子吸收光谱仪波长248.3nm处测定。本文还对方法的精密度和准确度等作了考查,结果令人满意。
【Abstract】 The methods are interfered badly by cobalt in determination of iron in cobalt sulfate.But the cobalt is extracted and separated with acetic ester in 7 mol/L chlorhydric acid medium in this method,and then anti-extract with water,the iron is determined in 248. 3 nm wave length of atomic absorption spectrograph with air-ethine flame in (1+9) chlorhydric acid mediun.The precision and accuracy of this method are inspected and the results are satisfied.
【关键词】 硫酸钴;
萃取;
反萃取;
原子吸收法;
【Key words】 Cobalt sulfate; Extraction; Anti-extraction; Atomic absorption;
【Key words】 Cobalt sulfate; Extraction; Anti-extraction; Atomic absorption;
- 【文献出处】 湖南有色金属 ,Hunan Nonferrous Metals , 编辑部邮箱 ,1999年03期
- 【分类号】O657.3
- 【被引频次】1
- 【下载频次】68