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某些含有偶氮基团新杂环息夫碱与钇(Ⅲ)配合物的合成与表征
Synthesis and Characterization of the New Heterocyclic Schiff Base With Azo group and Their Yttrium Complexes
【摘要】 本文由α—氨基—5—偶氮苯吡啶出发,分别与水杨醛、5硝基水杨醛及香草醛作用,合成了3种含有偶氮基团的杂环息夫碱.继而同三氯化钇反应,合成了3种新的配合物,通过元素分析、红外光谱、紫外可见光谱及热分析等方法研究了配合物的结构和性质.
【Abstract】 A new Schiff base was synthesized by the condensation of equimolar quantities of salicylaldehyde or o Vanillin and 2 amine 5 (4 nitro)phenylazo pyridine. Three new Yttrium Complexes of the type YL 3,YL " 3,YL 3Cl 3,Where L=nwely synthesized monobasic Schiff base were prepared in absolute ethanolic medium and characterized by elemental analysis, molar conductance, infrared spectra, electronic spectra and thermal analysis studies.
【基金】 河南省自然科学基金
- 【文献出处】 河南师范大学学报(自然科学版) ,JOURNAL OF HENAN NORMAL UNIVERSITY(NATURAL SCIENCE) , 编辑部邮箱 ,1999年01期
- 【分类号】O611.4,O614.322
- 【被引频次】1
- 【下载频次】43