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聚合硫酸铁絮凝剂的绝热合成研究

THE STUDIES ON HEAT INSULATION SYNTHESIS OF POLYFERRIC SULFATE FLOCCULANT

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【作者】 单忠健; 符建中; 廖为鑫;

【Author】 Shan Zhongjian Fu Jianzhong (Research Laboratory for Environmental Engineering,Chinese University of Mining and Technology, Beijing Campus,Beijing 100083) Liao Weixin (Formens Development Center for Environmentally Sound Science & Te

【机构】 中国矿业大学北京校区环境工程研究室!北京100083; 北京科技大学化学系!北京100083;

【摘要】 本文通过对聚合硫酸铁(PFS) 的动力学研究,发现PFS的合成温度控制在50 ℃以上就显著地提高了反应速度,缩短了反应周期。当相对水量C= 4 .5 ~5 .5 时,采用工业级硫酸亚铁为原料,在催化氧化作用下,可以实现PFS 的绝热合成工艺,去除加热设备,优化工艺过程。与直接氧化法PFS相比,绝热法聚合硫酸铁(HPFS) 具有更优的混凝性能。

【Abstract】 The kinetic characteristic was studied in the synthetic process of polyferric sulfate (PFS). It is found that the synthesis temperature of PFS,if controlled more than 50℃,can apparently raise the rate of the synthetic reaction of PFS and shorten the reaction period. When the value of relative water C is equal to 4.5 ~ 5.5,under the oxidation of catalyst,the heat insulation synthesis of PFS is realized with the raw Fe 2SO 4·7H 2O,getting rid of the heating equipment and economizing the processing. The heat insulation polyferric sulfate (HPFS) has better coagulating effect than the directly oxidizing PFS.

【关键词】 聚合硫酸铁; 絮凝剂; 绝热; 合成法;
【Key words】 polyferric sulfate; flocculant; heat insulation; synthesis.;
  • 【分类号】TQ138.11
  • 【被引频次】2
  • 【下载频次】79
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