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部分水溶性偶氮染料的光催化降解研究
KINETICS OF PHOTOCATALYTIC OXIDATION OF SOME AZOIC DYES IN WATER SOLUTION
【摘要】 本研究以高压汞灯为光源,系统地研究了16种偶氮染料在水溶液中的TiO2光催化降解,结果表明,这些偶氮染料的光解为一级动力学反应,采用TiO2光催化降解方法处理所研究的偶氮染料是可行的,井初步探讨了染料的结构与光解反应表观速率常数之间的关系。
【Abstract】 Photocatalytic degradation of 16 azo-dyes in TiO2 suspension and irradiated by a high pressure mercury lamp has been studied. The results show that the use of photocatalytic reaction to treat wastewater containing azo-dyes is feasible, and the photocalytic reaction of each azo-dye follows pseudo-first-order kinetics. The initial qualitative relationships between molecular structure and the determined pseudo-first-order photocatalytic degradation rate constants for the azo-dyes under study are discussed.
【基金】 国家自然科学基金(No.29807001);辽宁省自然科学基金(No.962118)
- 【文献出处】 环境化学 ,Environmental Chemistry , 编辑部邮箱 ,1999年03期
- 【分类号】X703
- 【被引频次】105
- 【下载频次】504