节点文献
水体表面微层中酞酸酯的光降解研究
PHOTODEGRADATION OF PHTHALIC ESTER IN WATER SURFACE MICROLAYER
【摘要】 研究了水体表面微层中酞酸酯化合物(DBP,DEHP)光降解的动力学,指出光催化降解符合一级动力学过程.实验证明:催化剂TiO2为2g·1-1,pH为6,并有H2O2存在时,是DBP,DEHP光降解的最佳条件;溶解氧增加有利于光降解.实际表面微层水样的光催化降解速率比模拟水样快.
【Abstract】 Photodegradation dynamics of phthalic ester in water surface microlayer was studied. The result suggests that photodegradation a first-order kinetics. Optimum conditions of photodegradation are: TiO2 is 2g·l-1; pH 6.0 and H2O2 existed. The increasing dissolved oxygen benefits photodegradation . The rate of photodegradation in actual water surface microlayer is faster than that in the simulated system.
【关键词】 表面微层;
酞酸酯;
光降解;
动力学;
【Key words】 surface microlayer; phthalic ester; photodegradation; dynamics.;
【Key words】 surface microlayer; phthalic ester; photodegradation; dynamics.;
【基金】 国家自然科学基金资助项目No:29577280
- 【文献出处】 环境化学 ,Environmental Chemistry , 编辑部邮箱 ,1999年02期
- 【分类号】O643.3
- 【被引频次】85
- 【下载频次】286