【摘要】 利用分子自组装方法合成了一种新奇的一维链状桥联双核铜配合物，用元素分析，红外光谱，电子光谱，摩尔电导，ｘ 射线四圆衍射等方法对其结构进行了表征，配合物分子中含两个铜（ Ｉ Ｉ）离子，金属离子之间通过 ４，４′联吡啶桥连起来，每个铜（ Ｉ Ｉ）离子处于由 ５ 个氮原子组成的 Ｄ３ｈ 对称性的三角双锥配位环境中。更多还原

【Abstract】 A novel one dimensional chain complex of bridged binuclear copper(II) was synthesized by molecular self\|assembly method.The structure of the titled compound was determined by Microanalysis, IR spectrum, electronic spectrum, molar conductivity and X\|ray four\|cycle diffractometer etc.The complex contains two copper(II)ions.Each one was bridged by 4,4`\|bipyridine . Each copper(II) is five\|coordinated by nitrogen atoms to form an almost regular trigonal bipyramidal geometry(D 3h )更多还原