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过氧化物交联聚烯烃弹性体的性能
Machanical properties of polyolefin elastomers crosslinked by peroxide
【摘要】 采用过氧化物交联,讨论了交联剂、共交联剂、补强填充剂以及增塑剂等对采用茂金属催化剂合成的乙烯-辛烯共聚物(POE)的物理机械性能的影响。结果表明,用过氧化物交联后,POE的拉伸强度、扯断伸长率和扯断永久变形大幅度下降。加入共交联剂,可以提高交联程度,缩短硫化时间。加入炭黑,可以起到补强作用,提高100%定伸应力、撕裂强度、拉伸强度和硬度,减小扯断伸长率和扯断永久变形。加入增塑剂降低了某些力学性能,但扯断伸长率增加,硬度减小。加入少量增塑剂,POE表现出优异的耐热老化性能。成功地开发了汽车散热管配方,产品基本性能达到德国DIN标准
【Abstract】 The influences of crosslinking agent,co-crosslinking agent, reinforcer and plasticizer on the mechanical properties of polyolefin elastomers(POE)were discussed with peroxide as crosslinking agent using metallocene catalyst. The results showed that the tensile strength, elongation at break and permanent set at break of POE decreased greatly after crosslinking. Addition of co-crosslink agent increased the degree of crosslinking and shortened the vulcanization time.Addition of carbon black had the effect of reinforcing, increased the 100% tensile modulus,tear strength,tensile strength and Shore A hardness, decreased the elongation at break and permanent set at break.Addition of plasticizer lowered some mechanical properties,but increased elongation at break and decreased Shore A hardness.When little amount of plasticizer was added,POE showed excellent aging property. A recipe of radiation hose was developed and its properties reached DIN standard.
【Key words】 polyolefin elastomers; metallocene catalyst; peroxide; crosslinking; mechanical property;
- 【文献出处】 合成橡胶工业 ,CHINA SYNTHETIC RUBBER INDUSTRY , 编辑部邮箱 ,1999年03期
- 【分类号】TQ334.2
- 【被引频次】27
- 【下载频次】326