【摘要】 将Ａ’－甲酰基苯并１５－冠－５和Ａ＇－甲酸基苯并１８－冠－６与壳聚糖（或交联壳聚糖）分子中的氨基反应，使冠醚单元接枝到高分子壳聚糖上，合成了Ｓｃｈｉｆｆ碱型壳聚糖冠醚。经元素分析、ＩＲ，Ｘ－粉末衍射分析和固体１３ＣＮＭＲ分析表征了其结构。实验结果表明壳聚精冠醚与预期结构相符。并初步考察了其对某些金属离子的吸附选择性。更多还原

【Abstract】 Pour new Schiff base chitosan-crown ethers were prepared by the reaction of 4’-formyl benzo-15-crown-5 and 4’-formyl benzo-18-crown-6 with chitosan or crosslinked chitosan. Their structureswere confirmed by infra-red spectra analysis, X-ray diffraction analysis and solid-state 13C NMR analysis.The experimental results showed that the structures of all chitosan-crown ethers were as expected.更多还原