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PZN-BT-PZT陶瓷的相结构与压电和介电性能研究
PHASE STRUCTURE AND DIELECTRIC PIEZOELECTRIC PROPERTIES OF PZN-BT-PZT CERAMICS
【摘要】 采用传统陶瓷工艺合成了(1-x)[0.94Pb(Zn1/3Nb2/3)O3-0.06BaTiO3]-xPb(Zr0.53Ti0.47)O3系陶瓷材料.结构分析表明,在x>0.30时,可以得到纯钙钛矿相,在x=0.50~0.60附近存在一个三方-四方共存的准同型相界,在此相界附近的压电、介电性能较好.同时还研究了退火处理对其介电、压电性能的影响,得到了平面机电耦合系数Kp=60%,压电系数d33=520pC/N左右,相对介电常数εm达到2万左右的压电材料.
【Abstract】 x)iO3]-xPb(Zr0.53Ti0.47)O3 ceramics were prepared by conventional ceramic processing. The results show that it is easy to obtain pure perovskite phase when x>0.30. When x=0.500.60, there is a rhombohedral/tetragonal morphotropic phase boundary. Better piezoelectric and dielectric properties exist near the phase boundary. After thermal annealing, improved piezoelectric and dielectric properties have been obtained. In this paper, Kp=60%,d33=520 pC/N, m20 000 are achieved.
【关键词】 铌锌酸铅-钛酸钡-锆钛酸铅陶瓷;
准同型相界;
压电和介电性能;
退火处理;
【Key words】 lead zinc niobate_barium titanate_lead zirconate titanate ceramics; morphotropic phase boundary; piezoelectric and dielectric properties; thermal annealing;
【Key words】 lead zinc niobate_barium titanate_lead zirconate titanate ceramics; morphotropic phase boundary; piezoelectric and dielectric properties; thermal annealing;
【基金】 西安交通大学博士学位论文基金
- 【文献出处】 硅酸盐学报 ,JOURNAL OF THE CHINESE CERAMIC SOCIETY , 编辑部邮箱 ,1999年02期
- 【分类号】TM282
- 【被引频次】7
- 【下载频次】162