节点文献
电化学法合成精细化学品──间接氧化制间硝基苯甲酸
Electrochemical Synthesis of Fine Chemicals──Indirect Oxidation of m-nitrotoluene with Cd(3+)/Cr2O72-
【摘要】 在分隔型电解槽中,用Pb/PbO2阳极将Cr(3+)氧化成为Cr2O7(2-);探讨了浓度、电流密度、温度等对电流效率的影响。在所推荐的条件下,阳极电流效率达到80%。再以CrO7为氧化剂将间硝基甲苯氧化成间硝基苯甲酸。研究表明,该过程具有收率高、产品质量好、污染小等优点。
【Abstract】 Electro-oxidation of Cr2(SO4)3 on Pb/PbO2 anode in H2SO4 solution was carried out in a dividedcell separated by an anion exchange membrane. The influences of factors, such as the concentration, currentdensity, temperature, etc., were investigated. Under the typical conditions appreciated, the anodic averagecurrent efficiency could reach 80%. The oxidation of m-nitrotoluene with Cr2O72- was also studied. Resultsshowed that the process employed gave higher yield, better product quality and less pollution.
【关键词】 电化学氧化;
间硝基苯甲酸;
间硝基甲苯;
【Key words】 electrochemical oxidation; m-nitrobenzoic acid; m-nitrotoluene;
【Key words】 electrochemical oxidation; m-nitrobenzoic acid; m-nitrotoluene;
【基金】 浙江省自然科学基金!296071;浙江大学曹光彪高科技发展基金;宁波市科研(攻关)基金
- 【文献出处】 高校化学工程学报 ,JOURNAL OF CHEMICAL ENGINEERING OF CHINESE UNIVERSITIES , 编辑部邮箱 ,1999年06期
- 【分类号】TQ226.1
- 【被引频次】10
- 【下载频次】210