节点文献
新型非耕地除草剂嘧磺隆合成反应动力学研究
Synthesis of Sulfometuron Methyl and its Kinetics
【摘要】 采用间歇玻璃反应釜进行糖精钠与氯甲酸甲酯在丙酮中的缩会反应和N-(2-甲氧甲酰基苯磺酰)氨基甲酸甲酯与2-氨基-4,6-二甲基嘧啶于抽余油中的缩合反应动力学研究。利用序贯实验设计法安排实验点,用Gauss-Newton法进行常微分模型的参数估值,得到了两个反应的动力学方程。
【Abstract】 The kinetics of the reaction of sodium saccharide with methyl chloroforamate and that of thereaction of 2-amino-4,6-dimethyl pyrimidine with n-(2-methoxycarbonyl phenyl-sulfonyl)-methylcarbamatein in solvent extrated residual oil were studied in an isothermal stirred batch reactor by usingthe sequential design method. The ldnetic models were proposed and the parameters in both modelswere estimated by Gauss-Newton method as followsand the reaction mechanisms were discussed
- 【文献出处】 高校化学工程学报 ,JOURNAL OF CHEMICAL ENGINEERING OF CHINESE UNIVERSITIES , 编辑部邮箱 ,1999年05期
- 【分类号】TQ45
- 【被引频次】8
- 【下载频次】69