【摘要】 利用红外、拉曼光谱研究一种手性schiff碱金属配合物N,N′双水杨醛缩1,2环己二胺合镍(Ⅱ)的结构特点。表明(R,R)—SALEN—Ni(Ⅱ)和(S,S)SALEN-Ni(Ⅱ)的光谱完全相同,而与外消旋体的光谱有很大差别更多还原

【Abstract】 FT Infrared and FT Raman spectra of (N, N’ bis(2 hydroxyphenylmethylene) 1,2 diaminocyclohexanatonickelous) (SALEN Ni(Ⅱ) were measured for studing the structure of a chiral Schiff base transition metal complex. The results show that some peaks in the spectra of (R,R) SALEN Ni(Ⅱ) are degenerated in the spectra of (±) SALEN Ni(Ⅱ).更多还原